Product ID:CLC-700/800 STARTER BLACK, F42-0402
MSDS Date:02/01/1994
FSC:6850
NIIN:00N070731
MSDS Number: CCNKQ

CANON USA INC

ONE CANON PLAZA
LAKE SUCCESS, NY 11042
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 516-328-5600

Preparer: JOSEPH PALMERI

Cage: 1BA63

CANON USA INC

LAKE SUCCESS, NY 11042 US

Telephone: 516-328-5600

Cage: 1BA63

IRON (III) OXIDE; (FERRITE POWDER MIXTURE) (CONTAINING INGS

CAS: 1309-37-1

RTECS: NO7400000

Fraction By Weight: 90-95%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG/M3 FUME (FE)

ZINC OXIDE (SARA 313) (CERCLA)

CAS: 1314-13-2

RTECS: ZH4810000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

COPPER OXIDE; (CUPRIC OXIDE)

CAS: 1317-38-0

RTECS: GL7900000

OSHA PEL 1 MG/M3 (CU)

ACGIH TLV: 1 MG/M3 (CU)

BISPHENOL A PROPYLENE OXIDE FUMARATE; (POLYESTER RESIN)

CAS: 39382-25-7

Fraction By Weight: 3-10%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <1%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

COPPER (METAL) (SARA 313) (CERCLA) (CONTAINING ING 7)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 12% MAX

OSHA PEL 0.1MG/M3 FUME;1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

COPPER COMPOUNDS

Fraction By Weight: <15% MAX

OSHA PEL 1 MG/M3 (CU)

ACGIH TLV: 1 MG/M3 (CU)

ZINC (METAL) (SARA 313) (CERCLA) (CONTAINING ING 9)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 12% MAX

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ZINC COMPOUNDS

Fraction By Weight: <15% MAX

OSHA PEL N/K

ACGIH TLV: N/K

EITHER BY LISTING/CHARACT. HOWEVER, UNDER

RTECS: 9999999ZZ

TIME OT DISP, WHETHER MATL CNTNG PROD/DERIVED FROM

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) >5000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:EXPECTED TO BE LOW
HAZARD FOR RECOMMENDED HANDLING. EYE:NO SPECIFIC HAZARDS KNOWN. MAY
CAUSE TRANSIENT IRRITATION. SKIN:EXPECTED TO BE LOW HAZARD FOR
RECOMMENDED HANDLING. NOT CLASSIF IED AS AN EYE/SKIN IRRITANT,
ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD (HCS).
INGESTION:EXPECTED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 65, PG 24-27, 1995:GROUP 2B.
Effects of Overexposure:HLTH HAZ:TO BE LOW INGEST HAZ. DATA FROM
SIMILAR TONER MATLS. CHRONIC:BASED UPON AVAIL DATA, HUMAN EXPOS TO
TONER HAS BEEN SHOWN TO CAUSE MIN RESP TRACT IRRIT AS MAY OCCUR
W/LG AMTS OF ANY NONTOXIC DU STS. THE RESULTS OF ONE ANIMAL STUDY
WHERE RATS INHALED TONER THAT WAS 10 TIMES MORE RESPIRABLE THAN
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES:ANY MATERIAL THAT CONTACTS EYE
SHOULD BE WASHED OUT IMMEDIATELY W/WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL AT TENTION IF SYMPTOMS OCCUR. SKIN:WASH W/SOAP & WATER.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGEST:DRINK 1-2 GLASSES
OF WATER. SEEK MEDICAL ATTENTION.

Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE (CO*2), OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NON-FLAMMABLE SOLID. POWDERED MATERIAL
MAY FORM EXPLOSIVE DUST-AIR MIXTURES. HAZARDOUS COMBUSTION
PRODUCTS:CARBON DIOXIDE, CARBON MONOXIDE.

Spill Release Procedures:SWEEP/SCOOP UP & REMOVE, PLACE IN A FIBER
CARTON. FLUSH RESIDUAL SPILL AREA W/WATER. THIS MATL HAS NOT BEEN
TESTED FOR ENVIRON EFTS. IN A SPILL SITUATION THIS MATL MAY BE
VISUALLY UNPLEASANT; HOWEVER, IT IS NOT EXPECTED TO CAUSE ANY
ADVERSE (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATHING DUST. USE W/ADEQUATE
VENTILATION. KEEP FROM CONTACT W/OXIDIZING MATERIALS. MINIMIZE DUST
GENERATION & ACCUMULATION.
Other Precautions:LOW HAZARD FOR RECOMMENDED HANDLING. REFER TO
PAMPHLET NO. 654, "PREVENTION OF FIRE & DUST EXPLOSIONS IN THE
CHEMICAL, DYE, PHARMACEUTICAL & PLASTICS INDUSTRIES". KEEP
CONTAINER CLOSED. IT IS GOOD IND US HYGIENE PRACTICE TO MIN EYE
CONT.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE SHOULD BE NEEDED.
Ventilation:GOOD VENT (TYPICALLY 4-6 ROOM VOLS PER HR) SHOULD BE USED.
VENT RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRACTICE SHOULD BE
FOLLOWED WHICH INCLUDES PREVENTING EYE CONT, MINIMIZING SKIN CONT,
INHAL.
Supplemental Safety and Health
EFTS OF OVEREXP:COMMERCIALLY AVAIL TONER WERE OBSERVED TO HAVE NO LUNG
CHANGES AT LOW EXPOS (MOST RELEVANT LEVEL TO POTNTL HUMAN EXPOS).
AT HIGHER LEVELS, A SLIGHT DEGREE OF LUNG FIBROSIS WAS OBSERVED
DUE TO EXCESSIVE AMTS OF DUST RETAINEDIN LUNGS FOR PRLNG INTERVAL.
SPILL PROC:ENVIRONMENTAL EFFECTS.

Spec Gravity:4-4.5 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID BLACK POWDER; SLIGHT PLASTIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE
& POSSIBLY TOXIC CHEMICALS SUCH AS CARBON MONOXIDE OR OXIDES OF
NITROGEN.

Waste Disposal Methods:INCIN/LANDFILL. CAN BE INCINERATED WHEN IN
COMPLIANCE W/LOC REGS. DISCHARGE, TREATMENT/DISP MAY BE SUBJECT TO
NATIONAL, STATE/LOC LAWS. EMPTY RECEPTACLE MAY BE RECYCLED. IF
DISCARDED IN ITS PURCHASED FORM, THIS PROD WOULD NOT BE A HAZ
WASTE (ING 10)

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